Title |
Hydrodynamic alignment and assembly of nanofibrils resulting in strong cellulose filaments
|
---|---|
Published in |
Nature Communications, June 2014
|
DOI | 10.1038/ncomms5018 |
Pubmed ID | |
Authors |
Karl M. O. Håkansson, Andreas B. Fall, Fredrik Lundell, Shun Yu, Christina Krywka, Stephan V. Roth, Gonzalo Santoro, Mathias Kvick, Lisa Prahl Wittberg, Lars Wågberg, L. Daniel Söderberg |
Abstract |
Cellulose nanofibrils can be obtained from trees and have considerable potential as a building block for biobased materials. In order to achieve good properties of these materials, the nanostructure must be controlled. Here we present a process combining hydrodynamic alignment with a dispersion-gel transition that produces homogeneous and smooth filaments from a low-concentration dispersion of cellulose nanofibrils in water. The preferential fibril orientation along the filament direction can be controlled by the process parameters. The specific ultimate strength is considerably higher than previously reported filaments made of cellulose nanofibrils. The strength is even in line with the strongest cellulose pulp fibres extracted from wood with the same degree of fibril alignment. Successful nanoscale alignment before gelation demands a proper separation of the timescales involved. Somewhat surprisingly, the device must not be too small if this is to be achieved. |
X Demographics
Geographical breakdown
Country | Count | As % |
---|---|---|
United Kingdom | 2 | 20% |
Sweden | 2 | 20% |
United States | 1 | 10% |
Denmark | 1 | 10% |
Chile | 1 | 10% |
France | 1 | 10% |
Unknown | 2 | 20% |
Demographic breakdown
Type | Count | As % |
---|---|---|
Members of the public | 8 | 80% |
Scientists | 2 | 20% |
Mendeley readers
Geographical breakdown
Country | Count | As % |
---|---|---|
Germany | 2 | <1% |
United States | 2 | <1% |
Sweden | 2 | <1% |
Switzerland | 1 | <1% |
Brazil | 1 | <1% |
Finland | 1 | <1% |
Netherlands | 1 | <1% |
Canada | 1 | <1% |
United Kingdom | 1 | <1% |
Other | 2 | <1% |
Unknown | 440 | 97% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Student > Ph. D. Student | 108 | 24% |
Researcher | 90 | 20% |
Student > Master | 61 | 13% |
Student > Doctoral Student | 29 | 6% |
Student > Bachelor | 20 | 4% |
Other | 56 | 12% |
Unknown | 90 | 20% |
Readers by discipline | Count | As % |
---|---|---|
Materials Science | 89 | 20% |
Engineering | 76 | 17% |
Chemistry | 72 | 16% |
Chemical Engineering | 19 | 4% |
Physics and Astronomy | 19 | 4% |
Other | 52 | 11% |
Unknown | 127 | 28% |