| Title |
Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry
|
|---|---|
| Published in |
Nature Chemistry, September 2018
|
| DOI | 10.1038/s41557-018-0107-7 |
| Pubmed ID | |
| Authors |
Kasper S. Pedersen, Panagiota Perlepe, Michael L. Aubrey, Daniel N. Woodruff, Sebastian E. Reyes-Lillo, Anders Reinholdt, Laura Voigt, Zheshen Li, Kasper Borup, Mathieu Rouzières, Dumitru Samohvalov, Fabrice Wilhelm, Andrei Rogalev, Jeffrey B. Neaton, Jeffrey R. Long, Rodolphe Clérac |
| Abstract |
The unique properties of graphene, transition-metal dichalcogenides and other two-dimensional (2D) materials have boosted interest in layered coordination solids. In particular, 2D materials that behave as both conductors and magnets could find applications in quantum magnetoelectronics and spintronics. Here, we report the synthesis of CrCl2(pyrazine)2, an air-stable layered solid, by reaction of CrCl2 with pyrazine (pyz). This compound displays a ferrimagnetic order below ∼55 K, reflecting the presence of strong magnetic interactions. Electrical conductivity measurements demonstrate that CrCl2(pyz)2 reaches a conductivity of 32 mS cm-1 at room temperature, which operates through a 2D hopping-based transport mechanism. These properties are induced by the redox-activity of the pyrazine ligand, which leads to a smearing of the Cr 3d and pyrazine π states. We suggest that the combination of redox-active ligands and reducing paramagnetic metal ions represents a general approach towards tuneable 2D materials that consist of charge-neutral layers and exhibit both long-range magnetic order and high electronic conductivity. |
X Demographics
The data shown below were collected from the profiles of 26 X users who shared this research output. Click here to find out more about how the information was compiled.
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| France | 9 | 35% |
| United States | 3 | 12% |
| United Kingdom | 2 | 8% |
| Spain | 1 | 4% |
| Poland | 1 | 4% |
| Denmark | 1 | 4% |
| Thailand | 1 | 4% |
| Unknown | 8 | 31% |
Demographic breakdown
| Type | Count | As % |
|---|---|---|
| Members of the public | 13 | 50% |
| Scientists | 11 | 42% |
| Science communicators (journalists, bloggers, editors) | 2 | 8% |
Mendeley readers
The data shown below were compiled from readership statistics for 170 Mendeley readers of this research output. Click here to see the associated Mendeley record.
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Unknown | 170 | 100% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Ph. D. Student | 44 | 26% |
| Researcher | 25 | 15% |
| Student > Master | 12 | 7% |
| Student > Doctoral Student | 9 | 5% |
| Student > Bachelor | 8 | 5% |
| Other | 29 | 17% |
| Unknown | 43 | 25% |
| Readers by discipline | Count | As % |
|---|---|---|
| Chemistry | 82 | 48% |
| Physics and Astronomy | 13 | 8% |
| Chemical Engineering | 8 | 5% |
| Materials Science | 6 | 4% |
| Engineering | 3 | 2% |
| Other | 4 | 2% |
| Unknown | 54 | 32% |
Attention Score in Context
This research output has an Altmetric Attention Score of 76. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 11 April 2021.
All research outputs
#549,701
of 25,040,629 outputs
Outputs from Nature Chemistry
#422
of 3,276 outputs
Outputs of similar age
#11,965
of 342,957 outputs
Outputs of similar age from Nature Chemistry
#9
of 54 outputs
Altmetric has tracked 25,040,629 research outputs across all sources so far. Compared to these this one has done particularly well and is in the 97th percentile: it's in the top 5% of all research outputs ever tracked by Altmetric.
So far Altmetric has tracked 3,276 research outputs from this source. They typically receive a lot more attention than average, with a mean Attention Score of 35.6. This one has done well, scoring higher than 87% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 342,957 tracked outputs that were published within six weeks on either side of this one in any source. This one has done particularly well, scoring higher than 96% of its contemporaries.
We're also able to compare this research output to 54 others from the same source and published within six weeks on either side of this one. This one has done well, scoring higher than 85% of its contemporaries.